Dougherty Modern physical organic chemistry, University Science, 2006. Carroll Perspectives on Structure and Mechanism in Organic Chemistry, Brooks-Cole, 1998 E. Dougherty, Modern Physical Organic Chemistry, University Science Books, 2006. ![]() Sundberg, Advanced Organic Chemistry(3rd ed.), Plenum, 1990, esp. Modern physical organic chemistry Eric V. Isaacs, Physical Organic Chemistry, Longmans, 1995. Richardson, Mechanism and Theory in Organic Chemistry, (3rd ed.), Harper and Row, 1987. There is no required textbook The following texts are recommended for further study and reference: T.H. Problems sets Two tests Final examination Monday, Wednesday and Friday, 9:30 a.m., room 115Ĭhemical kinetics and thermodynamics: rate laws, steady state approximation, pseudo-first-order reactions experimental determination of rate and equilibrium constants Eyring and Arrhenius equations, temperature effects on rate constants transition states, Hammond postulate, reaction coordinate diagrams principle of microscopic reversibility Application of kinetic methods in the study of reaction mechanism the rate law and the stoichiometry of the transition state pH rate profiles kinetic isotope effects structure-reactivity relationships, linear free energy relationships Hammett equation, Brønsted catalysis law solvent and medium effects Aromaticity, pericyclic reactions and orbital symmetry: aromaticity, Hückel rule, antiaromaticity FMO theory, Woodward-Hoffmann rules, Hückel-Möbius model pericyclic reactions: sigmatropic rearrangements, electrocyclic reactions, cycloadditions of Technology) and published by University Science Books in 2006. Chemistry 483a Topics in Mechanistic Organic Chemistry Lecturer: Free Download Modern Physical Organic Chemistrywritten by Eric V.
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